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Ergodicity and slowing down in glass-forming systems with soft potentials: no finite-temperature singularities

机译:具有软电势的玻璃成型系统的遍历性和减慢性:没有温度奇异点

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摘要

The aim of this paper is to discuss some basic notions regarding generic glass-forming systems composed of particles interacting via soft potentials. Excluding explicitly hard-core interaction, we discuss the so-called glass transition in which a supercooled amorphous state is formed, accompanied by a spectacular slowing down of relaxation to equilibrium, when the temperature is changed over a relatively small interval. Using the classical example of a 50-50 binary liquid of N particles with different interaction length scales, we show the following. (i) The system remains ergodic at all temperatures. (ii) The number of topologically distinct configurations can be computed, is temperature independent, and is exponential in N. (iii) Any two configurations in phase space can be connected using elementary moves whose number is polynomially bounded in N, showing that the graph of configurations has the small world property. (iv) The entropy of the system can be estimated at any temperature (or energy), and there is no Kauzmann crisis at any positive temperature. (v) The mechanism for the super-Arrhenius temperature dependence of the relaxation time is explained, connecting it to an entropic squeeze at the glass transition. (vi) There is no Vogel-Fulcher crisis at any finite temperature T>0.
机译:本文的目的是讨论有关由通过软势相互作用的粒子组成的通用玻璃形成系统的一些基本概念。除了明确的硬核相互作用外,我们讨论了所谓的玻璃化转变,其中形成了过冷的非晶态,并且当温度在相对较小的时间间隔内变化时,松弛从松弛到平衡的速度显着降低。使用具有不同相互作用长度尺度的N粒子的50-50二元液体的经典示例,我们显示以下内容。 (i)该系统在所有温度下均符合人体工程学。 (ii)可以计算拓扑上独立的构型的数量,它与温度无关,并且以N为指数。(iii)相空间中的任何两个构型都可以使用元素数为N的多项式连接的基本移动进行连接,如图所示的配置具有较小的世界属性。 (iv)可以在任何温度(或能量)下估计系统的熵,并且在任何正温度下都没有考兹曼危机。 (v)解释了弛豫时间与超阿雷尼乌斯温度相关的机理,并将其与玻璃化转变时的熵挤压联系起来。 (vi)在任何有限温度T> 0时都没有Vogel-Fulcher危机。

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